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High-temperature
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Measurement of high-temperature corrosion


Contact:

Dr. Vladislav Kolarik
Phone +49 721 4640-147
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Fraunhofer-Institut für Chemische Technologie ICT
Joseph-von-Fraunhofer-Straße 7
76327 Pfinztal


The research area of high-temperature materials involves the investigation and characterisation of the oxidation, corrosion and structural stability of (mostly) metal materials for high-temperature applications. The aim is to obtain information which will contribute to the further development of the material. Application fields include:

 

  • Coatings and materials for gas and steam turbines
  • Materials for high-temperature fuel cells
  • Heating elements based on Fe and Ni
  • Materials for vehicle technology

 

One research focus is in situ investigation via high-temperature X-ray diffractometry. The measurement system consists of an X-ray diffractometer with a high temperature chamber, isothermal measurement and a freely selectable temperature programme of up to 1600oC. This method enables:

 

  • In situ identification of corrosion products
  • Kinetic analysis of individual reactions
  • Simultaneous detection of heat expansion in every phase in the oxide layer and the substrate
  • In situ detection of mechanical stresses in the crystal lattice
  • In situ determination of recrystallisation processes

The analysis of the structure of the oxide layer and/or the material system is carried out via field emission scanning electron microscopy with site-resolved element analysis.

 

 

Application examples

 

  • Development of multifunctional coatings with thermal insulation and corrosion protection, using the particular properties of metal micro or nano sized particles
  • Phase stability of insulation layers made of partially stabilised ZrO2 and the development of new concepts for higher temperatures
  • MCrAIY coatings for turbine blades: formation of oxide coating and interdiffiusion, durability
  • Recrystallisation processes or structural degradation of alloys
  • Influence of steam on corrosion resistance of interconnects for high-temperature fuel cells
  • High-temperature oxidation of FeCrAl alloys.

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